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SURVEY OF CATALYST AND REDUCTANT EFFECTS ON OXORHENIUM CATALYZED DEOXYDEHYDRATION OF GLYCOLS
(2015-02-06)
Sustainable and renewable carbon sources are of great interest for long term succession of humankind. The sugars and polyols derived from cellulosic biomass offer such a sustainable feedstock considering cellulosic biomass ...
Spectroscopic and structural studies of ogranotin(IV) carboxylates and 1:1 chloride complexes /
(1983)
Organotin(IV) carboxylates of the formula {(C(, 6)H(, 5))(, 3)P(CH(, 2))(, 2)CO(, 2)SnR(, 3)}('+) X('-) where X is a halide or pseudohalide were prepared through the nucleophilic displacement of the anions in R(, 3)SnX ...
Interactions of organic S-nitroso and C-nitroso compounds with metalloporphyrins.
(2002)
Chapter 4 of this dissertation deals with the first isolable nitrone adducts of metalloporphyrins. Thus, the metalloporphyrin nitrone complexes (OEP)M(CO)(DMPO) (M = Ru, Os; DMPO = 5,5-dimethyl-1-pyrroline N-oxide) were ...
u-vinylidene and n-1-cyclopropenyliron complexes :
(1985)
The reaction chemistry of the bridging vinylidene iron dimers was explored and the chemistry of the double bond proved to be the most fertile. The bridging vinylidene was converted to the bridging alkylidene by protonation ...
Synthesis of nitrogen heterocycles via transition metal catalyzed reductive cyclizations of nitroaromatics.
(2003)
This research focuses on applying a catalyst system discovered in this laboratory, for the intermolecular allylic amination of alkenes with nitrobenzenes, to the synthesis of nitrogen heterocycles via an intramolecular ...
A study of the interactions of nitric oxide and nitric oxide containing molecules with heme proteins.
(2006)
The interactions of nitric oxide (NO), nitrite and organic nitroso compounds with heme proteins are biologically relevant. The formation of adducts between these NO-containing species and myoglobin (Mb) has served as a ...
BIONANOFIBER-BASED NANOSTRUCTURE FABRICATION AND APPLICATIONS
(2017-12)
Among various strategies for the synthesis and assembly of nano-scaled structures, bio-templating is an efficient method due to the unique physical and chemical properties of the template bionanomaterials, thus has experienced ...
Studies of the complexation reactions of polyether ionophore antibiotics monensin A and lasalocid A with lead(II), zinc, calcium and sodium cations.
(2000)
Lead-ionophore complexes of the form PbLX and PbL2 (L = monensin A or lasalocid A; X- = anion) were isolated and characterized by elemental analysis (X = Cl--) and ESI-MS (X = Cl --, NO3, CH3COO--). Changes in the UV-Vis ...
Part I. Kinetic studies of the complexation reactions of nickel(II) with hydroxamic acids in aqueous medium. Part II. Kinetic studies of the formation and dissociation reactions of ionomycin and 2,6-dimethylheptane-3,5-dione with nickel(II) and magnesium(II) in 80 percent methanol-water medium.
(1997)
The second part of the study involved the reactions of nickel(II) and magnesium(II), with the ionophore ionomycin and the model compound 2,6-dimethyl-3,5-heptanedione (DMHD). A detailed analysis of the kinetic data for ...