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Synthesis of nitrogen heterocycles via transition metal catalyzed reductive cyclizations of nitroaromatics.
(2003)
This research focuses on applying a catalyst system discovered in this laboratory, for the intermolecular allylic amination of alkenes with nitrobenzenes, to the synthesis of nitrogen heterocycles via an intramolecular ...
Synthesis, structure, and solution properties of benzoannelated cryptands.
(2006)
Cryptands An2.2.1 and An2.2.2 were synthesized by high dilution techniques. Attempts to produce An3.1.1 gave primarily the 2 + 2 addition product An3.1.1.3. X-ray crystallography, ESI-MS, and NMR techniques were used to ...
Tuning the frontier orbital character of iron-thiolate complexes.
(2000)
Another part of this work describes the solvatochromatic effect of CpFe(CO) 2(SC6H5) dissolved in different solvents. A blue shift in the UV-vis spectra occurs as CpFe(CO)2(SC6H 5) is solvated in more polar solvents, which ...
Mechanisms of electrophilic aromatic substitution reactions of (eta('6)-arene)molybdenum(phosphine)(, 3) complexes.
(2000)
The mechanism of protonation of (eta6-C6H 6)Mo(TRIPOD) (1) (TRIPOD = tris(1,1,1-diphenylphosphinoethyl)methyl ethane) to give [(eta6-C6H6)MoH(TRIPOD)] + was reported to involve a cyclohexadienyl intermediate. In this ...