Application of the local-composition model to a generalized equation of state for representing vapor-liquid equilibria of nonideal mixtures /
| dc.contributor.author | Li, Meng-hui, | en_US |
| dc.date.accessioned | 2013-08-16T12:29:04Z | |
| dc.date.available | 2013-08-16T12:29:04Z | |
| dc.date.issued | 1984 | en_US |
| dc.description.abstract | The statistical-mechanical local composition model has been applied to describe the composition dependence of a recently developed equation of state for use in vapor-liquid equilibria calculations. The composition-dependence for the mixture properties is derived from a local composition model expression for the Helmholtz free energy. The local composition mixing rules have been tested for a wide variety of binary mixtures: mixtures containing carbon dioxide, acetone, hydrogen sulfide, ammonia, methanol, ethanol, 1-propanol, water, etc. When compared with the conventional conformal solution model, a significant improvement is obtained for vapor-liquid equilibria predictions for strongly nonideal mixtures. This local composition model can be used to extend any corresponding-states type equation of state to mixtures. | en_US |
| dc.format.extent | ix, 116 leaves : | en_US |
| dc.identifier.uri | http://hdl.handle.net/11244/5235 | |
| dc.note | Source: Dissertation Abstracts International, Volume: 45-05, Section: B, page: 1533. | en_US |
| dc.subject | Engineering, Chemical. | en_US |
| dc.thesis.degree | Ph.D. | en_US |
| dc.thesis.degreeDiscipline | School of Chemical, Biological and Materials Engineering | en_US |
| dc.title | Application of the local-composition model to a generalized equation of state for representing vapor-liquid equilibria of nonideal mixtures / | en_US |
| dc.title.alternative | Application of the local-composition model to a generalized equation of state ... | en_US |
| dc.type | Thesis | en_US |
| ou.group | College of Engineering::School of Chemical, Biological and Materials Engineering | |
| ou.identifier | (UMI)AAI8418584 | en_US |
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