dc.contributor.advisor | Vasquez, Yolanda | |
dc.contributor.author | Khan, Muhammad | |
dc.contributor.author | Sulthana, Shoukath | |
dc.contributor.author | Weaver, Jimmie | |
dc.contributor.other | Oklahoma State University. Department of Physics | |
dc.date.accessioned | 2022-04-13T14:44:26Z | |
dc.date.available | 2022-04-13T14:44:26Z | |
dc.date.issued | 2022-04-19 | |
dc.identifier | oksd_URS_2022_khan | |
dc.identifier.citation | Khan, M., Sulthana, S., Weaver, J., & Vasquez, Y. (2022, April 19). Visible light-mediated photocatalytic azide-benzocycloheptene click reaction on gold surface by ATR-FTIR. Poster session presented at the Oklahoma State University Undergraduate Research Symposium, Stillwater, OK. | |
dc.identifier.uri | https://hdl.handle.net/11244/335217 | |
dc.description.abstract | In this work, a visible light-mediated [3+2] cycloaddition reaction between azide molecule and benzocycloheptene(BC7) terminated Au (111) surface was investigated. Exposure of the BC7 to photocatalyst and visible light facilitated the double bond isomerization of benzofused-cycloheptene, Z-BC7 to a strained and kinetically unstable alkene, E-BC7 to undergo cycloaddition with azide molecule to form triazoline ring structure. The reaction progress was monitored via attenuated total reflectance-Fourier transform infrared (ATR-FTIR). The strategy reported here offers spatial and temporal control of functionalization along with catch and release mechanisms due to the cleavable nature of the linker. | |
dc.description.sponsorship | Oklahoma State University. Research and Extension Experiences for Undergraduates | |
dc.description.sponsorship | National Science Foundation (U.S.) | |
dc.description.sponsorship | Oklahoma Center for the Advancement of Science and Technology | |
dc.format | application/pdf | |
dc.language | en_US | |
dc.publisher | Oklahoma State University | |
dc.rights | In the Oklahoma State University Library's institutional repository this paper is made available through the open access principles and the terms of agreement/consent between the author(s) and the publisher. The permission policy on the use, reproduction or distribution of the article falls under fair use for educational, scholarship, and research purposes. Contact Digital Resources and Discovery Services at lib-dls@okstate.edu or 405-744-9161 for further information. | |
dc.title | Visible light-mediated photocatalytic azide-benzocycloheptene click reaction on gold surface by ATR-FTIR | |
osu.filename | oksd_URS_2022_khan.pdf | |
dc.description.department | Chemistry | |
dc.type.genre | Poster | |
dc.type.material | Text | |
dc.type.material | Image | |
dc.subject.keywords | visible light | |
dc.subject.keywords | azides | |
dc.subject.keywords | BC7 SAMs Au | |
dc.subject.keywords | photocatalyst | |
dc.subject.keywords | click reaction | |