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SURVEY OF CATALYST AND REDUCTANT EFFECTS ON OXORHENIUM CATALYZED DEOXYDEHYDRATION OF GLYCOLS
(2015-02-06)
Sustainable and renewable carbon sources are of great interest for long term succession of humankind. The sugars and polyols derived from cellulosic biomass offer such a sustainable feedstock considering cellulosic biomass ...
BIONANOFIBER-BASED NANOSTRUCTURE FABRICATION AND APPLICATIONS
(2017-12)
Among various strategies for the synthesis and assembly of nano-scaled structures, bio-templating is an efficient method due to the unique physical and chemical properties of the template bionanomaterials, thus has experienced ...
The Effect Of Ligand Denticity In Stabilizing Actinide-Element Multiple Bond Functionalities
(2017-12)
Different synthetic approaches to the development of complexes with X-An=E and E=An=E functionalities (where An = U, Th) for use in studying the inverse trans influence (ITI) and the role f-orbitals play in early actinide ...
SYNTHESIS AND REDOX BEHAVIOR OF GROUP 8 METALLOPORPHYRINS AND RELATED COMPOUNDS
(2015)
This dissertation describes the Chemistry of Group 8 Metalloporphyrins and related compounds. Chapter one describes linkage isomerization in NOx-coordinated metal complexes with emphasis on Group 8 metals, and part of this ...
Phosphinimide Complexes of Molybdenum: Synthesis, and Reactivity of Metal-Element Multiple Bonds
(2018)
Methods were developed to synthesize new high-oxidation state molybdenum complexes supported by phosphinimide ligands ([R3P=N]-) that incorporate ligands with metal-element multiple bonds. A series of imido, oxido, and ...