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Spectroscopic and structural studies of ogranotin(IV) carboxylates and 1:1 chloride complexes /
(1983)
Organotin(IV) carboxylates of the formula {(C(, 6)H(, 5))(, 3)P(CH(, 2))(, 2)CO(, 2)SnR(, 3)}('+) X('-) where X is a halide or pseudohalide were prepared through the nucleophilic displacement of the anions in R(, 3)SnX ...
u-vinylidene and n-1-cyclopropenyliron complexes :
(1985)
The reaction chemistry of the bridging vinylidene iron dimers was explored and the chemistry of the double bond proved to be the most fertile. The bridging vinylidene was converted to the bridging alkylidene by protonation ...
Synthesis and characterization of stannoles.
(1980)
Treatment of the diiodotetraphenylstannole with excess lithium cyclopentadiene results in lithium 1,1-dicyclopentadienyl-1-iodo-2,3,4,5-tetraphenylstannole which, along with its bromine analog, are the only lithium salts ...
Synthesis and structure of cyclopentadienyl Tin(II) compounds /
(1983)
The boron trifluoride adduct of stannocene was reacted with the molybdenum hydride, HMo(CO)(, 3)((eta)('5)-C(, 5)H(, 5)). The compound was characterized by microanalytical analysis, melting point, NMR, ir, Mossbauer and ...
I. OVERVIEW OF THE METHODOLOGY OF TRANSITION METAL SUBSTITUTION KINETICS. II. SPECTROPHOTOMETRIC INVESTIGATION OF THE EXTENT OF ION-PAIRING BETWEEN AQUOPENTAAMMINERHODIUM(III) AND CHLORIDE IN ACIDIC AQUEOUS SOLUTION. III. THE SYNTHESIS OF TRANS-DIAQUOBIS(ETHYLENEDIAMINE)IRIDIUM(III). IV. THE KINETICS OF THE ANATION BY CHLORIDE OF TRANS-DIAQUOBIS(ETHYLENEDIAMINE)RHODIUM(III) IN ACIDIC AQUEOUS SOLUTION.
(1980)
The work reported here is part of an effort to develop a new method for studying the kinetics of transition metal substitution reactions. In the past, reactions have been studied at high, constant ionic strength following ...