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A study of the scope of metal-catalyzed allylic amination of olefins and an approach towards solid phase synthesis of unsymmetrical tertiary phosphines.
(1998)
A general route for the synthesis of N-alkoxy-N-alkylamidine hydrochlorides by reaction of organic nitriles with (N-alkyl-N-alkoxyammine)dimethylaluminum chloride (chapter 4, 26) is described.
Stereoselective Spirocyclizations Initiated by Metal Carbenes
(2019-05-10)
Within the field of drug design, there is a great interest in the development of synthetic libraries that mimic the structural complexity of natural product scaffolds. Recent cheminformatic analyses have revealed that 83% ...
STUDIES OF THE USE OF THE [2.2]PARACYCLOPHANE MOIETY TO MEDIATE INTERACTION BETWEEN METAL CENTERS AND ELECTROPOLYMERIZATION OF 2,2’-BITHIOPHENE IN MICELLAR MEDIA
(2013)
Organometallic polymers have been identified as a class of materials useful in various advanced applications due to their promising electrical, magnetic, optical and catalytic properties. Such properties depend on the ...
Synthesis of nitrogen heterocycles via transition metal catalyzed reductive cyclizations of nitroaromatics.
(2003)
This research focuses on applying a catalyst system discovered in this laboratory, for the intermolecular allylic amination of alkenes with nitrobenzenes, to the synthesis of nitrogen heterocycles via an intramolecular ...
Synthesis of symmetrical and optically active alpha-amino acids via homologation of nickel(II) complexed glycine Schiff bases.
(2007)
In order to overcome some of the limitations associated with the previously described Ni(II) complexed NGE a new generation of modular Ni(II) complexed NGE were introduced. The flexibility of this modular design has allowed ...
SELECTION OF METAL COMPLEX CATALYSTS BY TEMPLATING WITH TRANSITION STATE ANALOGS
(2015)
Abstract
Catalysts speed up reactions by providing an alternative, lower energy pathway for the reaction. However, the traditional method of catalyst discovery is time consuming and wastes chemicals. It is important to ...
Selective methods for the synthesis of highly-substituted cyclopentadienyl and indenyl ligands.
(2003)
Annulation methods involving cyclization of five-membered rings are regioselective approaches to highly substituted indenyl and cyclopentadienyl ligands for use in metallocene catalysts. The object of our research has been ...
Synthesis and characterization of polynitro-[2.2]paracyclophanes, a novel xylylene polymer, and poly(p-phenylene sulfoxide).
(The University of Oklahoma., 1999)
A less closely related polymer, poly(p-phenylene sulfoxide) (PPSX) (18) was synthesized by a novel homogenous oxidation of poly(p-phenylene sulfide) 17 with neat fuming nitric acid, fuming nitric acid in trifluoroacetic ...