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Palladium-catalyzed carboxylative coupling reactions of allyltributylstannanes and allyl chloride.
(2002)
Allyltins and allyl chloride are carboxylatively coupled under high carbon dioxide pressures in the presence of Pd(0) or Pd(II) catalyst. The effects of various Group 10 metal catalysts, phosphine ligands, and other, ...
Novel cobalt-mediated regio- and stereoselective radical cyclizations.
(1998)
Initial efforts focused on the intermolecular additions of the radicals to electron deficient double bonds, but they were unsuccessful. Efforts then focused on intramolecular cyclizations of 1-[(alkynyl)Co2(CO) 6]-5-hexenyl ...
Chemoenzymatic Transformations of Indole and Azaindole Containing Natural Product Analogs Using Promiscuous Prenyltransferases
(2021-12-17)
The overall aim of my work was to expand the practical utility of prenyltransferase-based biocatalysis as a tool in organic synthesis, natural product diversification, and drug discovery efforts. Aromatic prenyltransferases ...