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SYNTHESIS OF, AND APPLICATION OF THE COMPENSATED ARRHENIUS FORMULATION TO, ORGANIC CARBONATES AND OLIGOETHERS
(2013-12-20)
It has been proposed and shown that transport properties like self-diffusion and ionic conductivity in organic liquids are dependent on the dielectric constants and the activation energies in these liquids. The formal ...
Tuning the frontier orbital character of iron-thiolate complexes.
(2000)
Another part of this work describes the solvatochromatic effect of CpFe(CO) 2(SC6H5) dissolved in different solvents. A blue shift in the UV-vis spectra occurs as CpFe(CO)2(SC6H 5) is solvated in more polar solvents, which ...
Synthetic utility of phenyl radicals generated in situ and a mechanistic study of the unusual reactivity of 2-oxazolines with aldehydes.
(2007)
There are few references to this unusual reaction in the literature and no mechanistic studies. Therefore, a mechanistic study has been carried in order to provide a better understanding of the reaction. These studies ...
Studies of molecular architecture within solid polymer electrolytes and teichoic acid biopolymers from solid-state nuclear magnetic resonance spectroscopy.
(2007)
The unsuccessful collection of a 31P CP-MAS spectrum in frozen D2O suggests the presence of liquid water around LTA. 2H SSNMR were used to study the phase of the water environments for LTA dissolved in D2O at -25 and ...
Design and synthesis of bistable and tristable [2]catenanes as probes for non-covalent molecular interactions.
(2007)
With wider bis(p-benzyl)methyl spacers in 4,4'-dipyridinium macrocycles interlocked with the BPP34C10, four symmetric [2]catenanes have been studied. Symmetric blocking groups on tethers enabled either pathway for ...
Conversion of aromatic amines and N-aromatic amides to O-aromatic esters, biphenyls, aromatic halides and energetic materials via nitrosamide intermediates.
(2002)
These reactions can be carried out directly on aromatic amines (initial in situ acetanilide formation) to give aromatic acetates, and halides in good to excellent isolated yields. The mechanism, scope, potential utility ...
Mechanisms of electrophilic aromatic substitution reactions of (eta('6)-arene)molybdenum(phosphine)(, 3) complexes.
(2000)
The mechanism of protonation of (eta6-C6H 6)Mo(TRIPOD) (1) (TRIPOD = tris(1,1,1-diphenylphosphinoethyl)methyl ethane) to give [(eta6-C6H6)MoH(TRIPOD)] + was reported to involve a cyclohexadienyl intermediate. In this ...
An investigation into the natural products chemistry of the sea hare Aplysia dactylomela.
(1980)
A diterpenoid alcohol, C(, 20)H(, 32)O(, 3), which was characterized as a novel isomer of the known diterpenoid dolatriol, was also isolated from the chloroform extract.