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The Effect Of Ligand Denticity In Stabilizing Actinide-Element Multiple Bond Functionalities
(2017-12)
Different synthetic approaches to the development of complexes with X-An=E and E=An=E functionalities (where An = U, Th) for use in studying the inverse trans influence (ITI) and the role f-orbitals play in early actinide ...
Synthesis and characterization of stannoles.
(1980)
Treatment of the diiodotetraphenylstannole with excess lithium cyclopentadiene results in lithium 1,1-dicyclopentadienyl-1-iodo-2,3,4,5-tetraphenylstannole which, along with its bromine analog, are the only lithium salts ...
Synthesis and structure of cyclopentadienyl Tin(II) compounds /
(1983)
The boron trifluoride adduct of stannocene was reacted with the molybdenum hydride, HMo(CO)(, 3)((eta)('5)-C(, 5)H(, 5)). The compound was characterized by microanalytical analysis, melting point, NMR, ir, Mossbauer and ...
Characterization of pure and phase-stabilized sodium phosphate.
(1998)
This work illustrates the necessity of using a variety of techniques when characterizing these systems, which undergo complex structural changes that cannot be completely characterized using a single technique. The XRD ...
From nitrite reductase to Alzheimer's disease: Design, synthesis, and reactivity of new nitrogen-, oxygen-, and sulfur-containing ligands and their copper complexes.
(2006)
Transition metal ions are essential for a wide range of biochemical transformations and are found in more than one half of all known enzymes. Our interest in the bioinorganic chemistry of copper prompted us to develop new ...
Synthesis and Redox Behavior of Ruthenium Nitrosyl Porphyrin Complexes
(2022-05-13)
This dissertation details the synthesis, characterization, and redox behavior of various six-coordinate ruthenium nitrosyl porphyrin complexes. The primary focus of this work is centered on factors that impact the redox ...
Interactions of nitric oxide and nitrosamines with group 8 metalloporphyrins.
(2007)
Chapter 1 of this dissertation introduces the importance of nitric oxide in biological systems.
Synthesis, structure, and solution properties of benzoannelated cryptands.
(2006)
Cryptands An2.2.1 and An2.2.2 were synthesized by high dilution techniques. Attempts to produce An3.1.1 gave primarily the 2 + 2 addition product An3.1.1.3. X-ray crystallography, ESI-MS, and NMR techniques were used to ...
I. OVERVIEW OF THE METHODOLOGY OF TRANSITION METAL SUBSTITUTION KINETICS. II. SPECTROPHOTOMETRIC INVESTIGATION OF THE EXTENT OF ION-PAIRING BETWEEN AQUOPENTAAMMINERHODIUM(III) AND CHLORIDE IN ACIDIC AQUEOUS SOLUTION. III. THE SYNTHESIS OF TRANS-DIAQUOBIS(ETHYLENEDIAMINE)IRIDIUM(III). IV. THE KINETICS OF THE ANATION BY CHLORIDE OF TRANS-DIAQUOBIS(ETHYLENEDIAMINE)RHODIUM(III) IN ACIDIC AQUEOUS SOLUTION.
(1980)
The work reported here is part of an effort to develop a new method for studying the kinetics of transition metal substitution reactions. In the past, reactions have been studied at high, constant ionic strength following ...