Browsing OU - Dissertations by Subject "Radicals (Chemistry)"
Now showing items 1-2 of 2
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Novel cobalt-mediated regio- and stereoselective radical cyclizations.
(1998)Initial efforts focused on the intermolecular additions of the radicals to electron deficient double bonds, but they were unsuccessful. Efforts then focused on intramolecular cyclizations of 1-[(alkynyl)Co2(CO) 6]-5-hexenyl ... -
Synthetic utility of phenyl radicals generated in situ and a mechanistic study of the unusual reactivity of 2-oxazolines with aldehydes.
(2007)There are few references to this unusual reaction in the literature and no mechanistic studies. Therefore, a mechanistic study has been carried in order to provide a better understanding of the reaction. These studies ...